Natural Gas Cleansing

To date Tenoroc’s primary development effort has been directed toward the condensation based separation of carbon dioxide from methane (natural gas) to create a means to capitalize on the substantial natural gas reserves deemed too contaminated with carbon dioxide and/or hydrogen sulfide to be economically viable.

In recent years, demand for natural gas has grown substantially. However, as the natural gas industry in the United States becomes more mature, domestically available resources become harder to find and produce. As large, conventional natural gas deposits are extracted, the natural gas left in the ground is commonly found in less conventional deposits, which are harder to discover and produce than has historically been the case. Massive gas reserves, already identified, are too contaminated for exploitation and remain unused, too expensive to clean. Like oil, natural gas is often found underwater in offshore gas fields such as the North Sea, Corrib Gas Field off Ireland, and the Scotian Shelf near Sable Island. The technology utilized to extract and transport offshore natural gas is different from land-based fields in that a few, very large rigs are usually used, due to the cost and logistical difficulties in working over water. Rising gas prices have encouraged drillers to revisit fields that, until now, were not considered economically viable. For example, McMoran Exploration has passed a drilling depth of over 32,000 feet (the deepest test well in the history of gas production) at the Blackbeard site in the Gulf of Mexico. ExxonMobil’s drill rig had reached 30,000 feet by 2006 without finding gas; ExxonMobil abandoned the site. The Tenoroc technology is directed towards allowing for the use of known gas reserves that have high levels of contamination, reducing or eliminating the substantial risk and expense of exploration.

 

Advantages Over Today’s Method of Natural Gas Cleansing

Currently, contaminated natural gas is cleansed predominately by percolating it through massive tanks of absorbing liquids, a method called Acid Gas Removal (AGR), or to a far lesser extent by membrane filtering. AGR plants have a very large footprint, limiting their use in remote land based locations and on offshore platforms. More importantly, these plants can only process limited levels of contamination before cleansing becomes too costly. These AGR plants require a great deal of heat and energy to remove the absorbed contaminants from the absorbing liquids in a process called re-boiling. The frequency of re-boiling increases with higher levels of contamination. During the re-boiling process the volatile absorbing liquids, as well as any natural gas that was absorbed, are emitted into the atmosphere. These emissions are significant greenhouse gases that contribute to atmospheric pollution. The natural gas emissions represent lost profits. The absorbing liquids that are emitted must be continually replaced, adding to processing costs. Tenoroc’s technology addresses these environmental and financial disadvantages. Reportedly, some AGR type systems and newly developed membrane processes can process higher CO2 contamination levels than conventional AGR plants; however these systems have not found their way into the mainstream, presumably due to processing and capital expense. In addition to being able to cleanse higher levels of contamination, the Tenoroc nozzles may have the potential to improve upon or replace these current natural gas cleansing methods.

 

Developing the Technology for Natural Gas Cleansing

Tenoroc researchers are currently working with a two-component mixture of nitrogen and carbon dioxide as a test gas to aid in developing the separation nozzle design in a laboratory facility. The two-component mixture has characteristics that simulate many separation scenarios such as carbon dioxide separation from methane, carbon dioxide separation from exhaust gases having high levels of nitrogen, and carbon dioxide separation from hydrogen. The principle behind the Tenoroc nozzle is that when methane contaminated by carbon dioxide (CO2) flows through the Tenoroc nozzle, the pressure and temperature drop that occur in the nozzle will cause the CO2 to change phase/condense from a gas to a liquid or solid, leaving the methane in a gaseous phase. At this point the liquid or solid CO2 will be much heavier than the gaseous methane. The tremendous gravity in the curved nozzle will force the now liquid or solid CO2 to the outside wall away from the methane, where it will be siphoned off.

The advantages of the Tenoroc technology in this market are:

  1. Facilitating recovery of known non-producing reserves with massive corresponding exploration cost savings
  2. Ability to cleanse higher levels of contamination
  3. Low capital equipment cost
  4. Nozzles have no moving parts
  5. Lower operations costs
  6. Reduced or eliminated discharges
  7. Small footprint and mobility
 

Isotope Enrichment

Tenoroc’s gas-to-gas nozzle technology has several potential applications. The gas-to-gas application of greatest interest to Tenoroc is isotope enrichment, including the production of isotopically pure silicon used to produce semiconductor wafers. Pure silicon has been studied by the semiconductor industry for years and is believed by many to be the answer to the debilitating heat generated by today’s computers that results in slower processing speed. There are patents on the use of this pure silicon material in wafer manufacture, but no one has been able to purify the gas that silicon is made from at a reasonable cost or in the quantities needed for commercial application. It is generally understood that one source of this material had been the former Soviet Union military centrifuge systems. It was apparently too expensive and the volume necessary to create a viable market for isotopically pure wafers was not available. In pursuit of a solution to heat buildup in computers, a publicly traded company was established to acquire isotopically pure gases, used to produce silicon, from the Soviet Union. That company was unsuccessful in this effort. The Tenoroc technology could be the answer to the ongoing industry challenge of heat buildup, facilitating the production of faster microprocessors.

In addition to the promise that isotopically pure silicon wafers hold for today’s computer technology, researchers have begun to experiment with nano-based technology that is also built upon isotopically pure silicon. This experimental nano technology indicates the possibility of exponentially increased processing speeds.

 

Other Applications:

  1. Refrigeration
  2. Desalination
  3. Carbon Capture
  4. Industrial gas separations
  5. Medical and industrial isotopes
  6. Oil / water separations